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Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with [Cl] present: an experimental and theoretical study

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 56-67 doi: 10.1007/s11705-022-2185-8

摘要： Separation of vanadium from black shale leaching solution at low pH is very meaningful, which can effectively avoid the generation of alkali neutralization slag and the resulting vanadium loss. In this study, coordination mechanism of vanadium in acid leaching solution at low pH was investigated with the intervention of chloride ions. Under the conditions of pH 0.8, di-(2-ethylhexyl)phosphoric acid concentration of 20%, phase ratio of 1:2, and extraction time of 8 min, the vanadium extraction could reach 80.00%. The Fourier transform infrared and electrospray ionization results reveal that, despite the fact that the chloride ion in the leachate could significantly promote vanadium extraction, the chloride ion does not enter the organic phase, indicating an intriguing phenomenon. Among Cl−–V, SO42−–V, and H2O–V, the V–Cl bond is longer and the potential difference between coordinate ions and vanadium is smaller. Therefore, VO2+ gets easily desorbed with chloride ions and enter the organic phase. At the same time, the hydrogen ions of di-(2-ethylhexyl)phosphoric acid also enter the water phase more easily, which reduces the pH required for the extraction reaction.

关键词： vanadium     black shale     solvent extraction     high acidity extraction    

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The Fast Road of Shale Gas Development in China —Reflections on Building a Special Test Areas for NationalShale Gas Development

Da-wei Zhang

《工程管理前沿（英文）》 2015年 第2卷 第4期   页码 364-372 doi: 10.15302/J-FEM-2015062

摘要： China’s shale gas development has had a good start. It is necessary that the developers take advantage of the opportunity to make further efforts to promote shale gas development in China, in particular by rolling out a comprehensive plan on a national level. The author makes a proposal to establish a special shale gas test area in and adjacent to the Sichuan Basin as the most important way to promote the rapid development of shale gas in China. For this purpose, the author analyzes the current situation and problems of shale gas development in China, addresses the necessity and feasibility of establishing a special test area for shale gas development, and draws up the scope of this shale gas special test area of about 450 thousand square kilometers, covering Sichuan, Chongqing, Guizhou, and part of Yunnan, Hunan, Hubei provinces, and proposes the establishment of a shale gas test area in China. This consists of an overall plan, targets, and contents in 10 aspects, along with organization and implementation modes. The shale gas exploration and development in the shale gas zones is promoted vigorously by introducing special policies and innovating exploration, development and utilization model. While at the same time, the shale gas zones of continental facies in the Ordos Basin and marine-terrigenous facies in South Hubei Basin will be established. The experiences of the reform in the shale gas zones will be the good practice for the reform of petroleum organization system.

关键词： China     shale gas     exploration and development     reform     special shale gas test area (shale gas zone)    

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Preparation of nZVI embedded modified mesoporous carbon for catalytic persulfate to degradation of reactive black

《环境科学与工程前沿（英文）》 2021年 第15卷 第5期 doi: 10.1007/s11783-020-1372-4

摘要：

• The MCNZVI is prepared as an interesting material for PS activation.

关键词： MCNZVI     Core-shell structure     Reactive Black 5     Persulfate     Mechanism    

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A Review on Shale Gas Development in Fuling

Zhi-gang Wang

《工程管理前沿（英文）》 2015年 第2卷 第1期   页码 76-81 doi: 10.15302/J-FEM-2015011

摘要： The Fuling Marine Shale Deposit contains vast gas resources. Due to tectonic activities, complex surface and geological conditions, significant differences make it unlike that of North America. Thus, it is not suitable to completely copy the technology and the development model from North America. Therefore we need engineering technology and a business development model fit for Fuling Shale Gas Development (FSGD). Through difficulties and characteristics analysis of the shale gas development area, we determined geological engineering design methods and integrated workflow, established a series of the core technologies, including horizontal well drilling with long laterals, staged fracturing and completion technology, developed main fluids, tools and equipment, put forward “well factory” mode in mountain region and “full cycle learning and system optimization” management methods. Break through was made in China’s first large-scale shale gas fields commercial development. By the end of 2014, production capacity reached 25 × 10 m /a, and cumulative gas production reached 12.24 × 10 m , which made a solid foundation to build production capacity of 50 × 10 m /a in 2015 and 100 × 10 m /a in 2017. Not only has FSGD established a demonstration for the other shale gas fields’ development, but also will be taken as reference to other large and extra-large construction projects of the industry.

关键词： Fuling     shale gas     drilling and completion     staged fracturing     learning curve     capacity building     commercial development    

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Engineering Philosophy-based Reflections on Efficient Development of Shale Gas in China

He Liu,Jian-wen Yan,Qing-hai Yang

《工程管理前沿（英文）》 2015年 第2卷 第2期   页码 108-113 doi: 10.15302/J-FEM-2015030

摘要： The Shale Gas Revolution began to have a significant impact on global supply and demand of natural gas; also the price trend of natural gas has been greatly affected. This phenomenon raised concerns among natural gas producers and consumers. China has abundant shale gas resources, but the development scale is small while facing problems including weak exploration and evaluation basis, overlapping royalties, complex terrestrial environment, lack of technical practices and accumulation, inadequate management and regulatory mechanisms, etc. To overcome these challenges for large-scale shale gas development, we believe that shale gas development is not only a single technical problem, but a systematic engineering demanding multidisciplinary research that will be bound to spread to humans, nature, and society. Therefore, to ensure the healthy development of China’s shale gas, it is required to coordinate global and local relationships, engineering and community relations, as well as to break up the conflicts between engineering and nature, engineering and economy, along with engineering and society.

关键词： shale gas development     engineering     energy revolution     engineering philosophy     reflections    

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CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

《能源前沿（英文）》 2023年 第17卷 第3期   页码 428-445 doi: 10.1007/s11708-023-0865-9

摘要： In this work, using fractured shale cores, isothermal adsorption experiments and core flooding tests were conducted to investigate the performance of injecting different gases to enhance shale gas recovery and CO2 geological storage efficiency under real reservoir conditions. The adsorption process of shale to different gases was in agreement with the extended-Langmuir model, and the adsorption capacity of CO2 was the largest, followed by CH4, and that of N2 was the smallest of the three pure gases. In addition, when the CO2 concentration in the mixed gas exceeded 50%, the adsorption capacity of the mixed gas was greater than that of CH4, and had a strong competitive adsorption effect. For the core flooding tests, pure gas injection showed that the breakthrough time of CO2 was longer than that of N2, and the CH4 recovery factor at the breakthrough time (RCH4) was also higher than that of N2. The RCH4 of CO2 gas injection was approximately 44.09%, while the RCH4 of N2 was only 31.63%. For CO2/N2 mixed gas injection, with the increase of CO2 concentration, the RCH4 increased, and the RCH4 for mixed gas CO2/N2 = 8:2 was close to that of pure CO2, about 40.24%. Moreover, the breakthrough time of N2 in mixed gas was not much different from that when pure N2 was injected, while the breakthrough time of CO2 was prolonged, which indicated that with the increase of N2 concentration in the mixed gas, the breakthrough time of CO2 could be extended. Furthermore, an abnormal surge of N2 concentration in the produced gas was observed after N2 breakthrough. In regards to CO2 storage efficiency (Sstorage-CO2), as the CO2 concentration increased, Sstorage-CO2 also increased. The Sstorage-CO2 of the pure CO2 gas injection was about 35.96%, while for mixed gas CO2/N2 = 8:2, Sstorage-CO2 was about 32.28%.

关键词： shale gas     gas injection     competitive adsorption     enhanced shale gas recovery     CO2 geological storage    

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Discovery of Fuling Shale Gas Field and its prospects

Xusheng GUO, Yuping LI, Jinlei LI, Minggang FENG, Hua DUAN

《能源前沿（英文）》 2019年 第13卷 第2期   页码 354-366 doi: 10.1007/s11708-018-0581-z

摘要： A series of breakthroughs have been made in the understanding, evaluation, and exploration of shale gas from discovery, environmental protection to efficient exploration in the discovering of Fuling Gas Field. By revealing the positive correlation between organic carbon content and siliceous mineral content of shale deposited in deep shelf, dynamic preservation mechanism of “early retention and late deformation,” it is clarified that the shales deposited in deep shelf are the most favorable for shale gas generation, storage and fracturing. The preserving conditions determine the levels of shale gas accumulation, thus the evaluation concept of taking the quality of the shale as the base and the preserving conditions as key is proposed, the evaluation system for strategic selection of favorable zones is established for marine shale gas exploration in Southern China. Moreover, the “sweet point” seismic forecasting technologies for marine shale gas, the “six properties” logging technologies for evaluating shale gas layers, the technologies for quick and efficient drilling of horizontal well groups, and the fracturing technologies for composite fractures for horizontal wells are invented. The paper discussed the exploration prospect of shale gas in the shales of Wufeng-Longmaxi Formation in great depth in Sichuan Basin, shale gas exploration in the outer region of the south, and continental shale gas exploration in China.

关键词： shale gas     accumulation laws     exploration technologies     Longmaxi Formation     Fuling Shale Gas Field     Sichuan Basin    

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Characteristics of typical dissolved black carbons and their influence on the formation of disinfection

《环境科学与工程前沿（英文）》 2022年 第16卷 第12期 doi: 10.1007/s11783-022-1585-9

摘要：

● The physicochemical and structural properties of DBC were characterized.

关键词： Dissolved black carbon (DBC)     Chlorine     Chloramine     Disinfection by-products (DBPs)     Disinfection by-products formation potential (DBPFP)    

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oxide for active and intelligent packaging: comparison of anthocyanins source from purple tomato or black

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 704-715 doi: 10.1007/s11705-022-2270-z

摘要： The multifunctional films was prepared by blending chitosan and nano-ZnO with purple tomato anthocyanins or black wolfberry anthocyanins. The properties of films functioned by anthocyanins source and nano-ZnO content were studied. It was found purple tomato anthocyanins showed more significant color change against pH than black wolfberry anthocyanins. The nano-ZnO were widely dispersed in matrix and enhanced the compatibility of anthocyanins with chitosan. However, the anthocyanins source influenced the properties of the films more slightly than nano-ZnO addition. The tensile strength, antioxidant and antibacterial effects of the chitosan films dramatically increased after cooperated by nano-ZnO and anthocyanins, which also enhanced with increase of nano-ZnO content, whereas the elongation at break of the composite films decreased. Especially, the anthocyanin and nano-ZnO promoted the antibacterial activity of films synergistically. Composite films made from black wolfberry anthocyanins exhibited higher mechanical performance than those made from purple tomato anthocyanins but weaker antibacterial effects. The purple tomato anthocyanins/chitosan and nano-ZnO/purple tomato anthocyanins/chitosan films effectively reflected pork spoilage, changing their colors from dark green to brown, indicating the potential for applications in active and intelligent food packaging.

关键词： bio-based     multifunction     colorimetric indicator     active and intelligent packaging    

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Property-performance relationship of core-shell structured black TiO photocatalyst for environmental

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1711-3

摘要：

● Properties and performance relationship of CSBT photocatalyst were investigated.

关键词： Black TiO2     Core-shell structure     Property-performance relationship     Agro-industrial effluent     Environmental remediation    

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A review on co-pyrolysis of coal and oil shale to produce coke

Xiangchun Liu, Ping Cui, Qiang Ling, Zhigang Zhao, Ruilun Xie

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 504-512 doi: 10.1007/s11705-019-1850-z

摘要： It has become the top priority for coking industry to rationally use and enlarge coking coal resources because of the shortage of the resources. This review focuses on the potential utilization of oil shale (OS) as a feedstock for coal-blending coking, in which the initial and basic step is pyrolysis. However, OS has a high ash content. If such OS is directly used for coal-blending coking, the coke product will not meet market demand. Therefore, this review firstly summarizes separation and beneficiation techniques for organic matter in OS, and provides an overview on coal and OS pyrolysis through several viewpoints (e.g., pyrolysis process, phenomena, and products). Then the exploratory studies on co-pyrolysis of coal with OS, including co-pyrolysis phenomena and process mechanism, are discussed. Finally, co-pyrolysis of different ranks of coals with OS in terms of coal-blending coking, where further research deserves to be performed, is suggested.

关键词： coal     oil shale     co-pyrolysis     coal blending coking     coke    

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Community diversity and distribution of ammonia-oxidizing archaea in marsh wetlands in the black soil

Chunhong Chen, Hong Liang, Dawen Gao

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1146-z

摘要：

AOA amoA genes in the soils of the two wetlands affiliated with three lineages.

The main drivers of AOA community were pH and total organic carbon and ammonium.

The soil characteristics rather than the vegetation control the AOA community.

关键词： Ammonia-oxidizing archaea     amoA gene     Freshwater marsh     Diversity     Distribution    

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中美页岩气成藏条件、分布特征差异研究与启示

李建忠,李登华,董大忠,王社教

《中国工程科学》 2012年 第14卷 第6期   页码 56-63

摘要：

美国页岩气大多为海相热成因型，产气页岩主要分布在前陆和克拉通盆地的泥盆—石炭系，埋藏深度一般为1 500~3 500 m。我国页岩分为海相、海陆过渡相与煤系、湖相三类，其中海相页岩主要发育在坳拉槽和克拉通盆地的下古生界，富有机质集中段分布稳定，热成熟度偏高，有较高的含气量，勘探前景最好；海陆过渡相与煤系页岩主要发育在大型坳陷和前陆盆地，层系以石炭系—侏罗系为主，没有明显的富有机质集中段，含气量差别较大，勘探潜力有待落实；湖相页岩主要发育在中、新生代陆相盆地，富有机质集中段厚度大，成熟度较高的凹陷中心区可能具有一定资源前景。预测我国页岩气勘探将经历较长的探索期，未来年产量可达500亿～600亿m3规模。

关键词： 页岩气     成藏条件     分布特征     富有机质页岩     中美对比     启示    

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Contribution of black carbon to nonlinearity of sorption and desorption of acetochlor on sediment

Jianqiu LIU, Yaobin ZHANG, Hong CHEN, Yazhi ZHAO, Xie QUAN

《环境科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 69-74 doi: 10.1007/s11783-008-0076-y

摘要： In order to investigate the contribution of various black carbon (BC) contents to nonlinearity of sorption and desorption isotherms for acetochlor on sediment, equilibrium sorption and desorption isotherms were determined to measure sorption and desorption of acetochlor in sediment amended with various amounts of BC. In this paper, two types of BC referred to as BC400 and BC500 were prepared at 400°C and 500°C, respectively. Higher preparation temperature facilitated the formation of micropores on BC to enhance its sorption capacity. Increase of the BC content obviously increased the sorption amount and reduced the desorption amount for acetochlor. When the BC500 contents in total organic carbon (TOC) increased from 0 to 60%, Freundlich sorption coefficient ( ) increased from 4.07 to 35.74, and desorption hysteresis became gradually obvious. When the content of BC in TOC was lower than 23%, the sorption isotherm had a significant linear correlation ( = 0.05). In case of desorption, a significant nonlinear change could be observed when the content of BC was up to 13%. Increase of BC content in the sediment would result in shifting the sorption-desorption isotherms from linearity to nonlinearity, which indicated that contribution of BC to nonlinear adsorption fraction became gradually remarkable.

关键词： black carbon (BC)     sorption     desorption     sediment    

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Effect of carbon black on the dynamic moduli of asphalt mixtures and its master curves

Chuangmin LI, Fanbo NING, Yuanyuan LI

《结构与土木工程前沿（英文）》 2019年 第13卷 第4期   页码 918-925 doi: 10.1007/s11709-019-0526-6

摘要： Modulus is one of the main parameters during the design of asphalt pavement structure, the newest specifications of China gives the dynamic moduli ranges of commonly used asphalt mixtures with base asphalt (BA) or styrene-butadiene-styrene modified asphalt (SBS MA), while the moduli ranges of mixtures with carbon black modified asphalt (CB MA) are not recommended. To investigate the CB effect on the dynamic moduli of CB MA mixtures, one commonly used asphalt mixture (AC-20) was designed with BA, SBS MA, and CB MA, respectively. Then, the uniaxial compression dynamic modulus tests were conducted at different temperatures and loading frequencies, the master curves of asphalt mixtures were analyzed based on the time-temperature equivalence principle. The results show that ith increasing loading frequency, the temperature dependence of dynamic moduli of all asphalt mixtures tend to be less obvious. Both SBS and CB can decrease the temperature sensitivity of asphalt mixture, the SBS MA mixture has the lowest temperature sensitivity, followed by CB MA and BA mixture. In addition, CB and SBS can obviously improve the dynamic modulus of the BA mixture, enhance the anti-deformation performance of pavement structure, and the improvement effect of CB is almost the same with SBS.

关键词： dynamic modulus     carbon black     master curve     modified asphalt     asphalt mixture    

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标题 作者 时间 类型 操作

Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with [Cl] present: an experimental and theoretical study

期刊论文

The Fast Road of Shale Gas Development in China —Reflections on Building a Special Test Areas for NationalShale Gas Development

Da-wei Zhang

期刊论文

Preparation of nZVI embedded modified mesoporous carbon for catalytic persulfate to degradation of reactive black

期刊论文

A Review on Shale Gas Development in Fuling

Zhi-gang Wang

期刊论文

Engineering Philosophy-based Reflections on Efficient Development of Shale Gas in China

He Liu,Jian-wen Yan,Qing-hai Yang

期刊论文

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

期刊论文

Discovery of Fuling Shale Gas Field and its prospects

Xusheng GUO, Yuping LI, Jinlei LI, Minggang FENG, Hua DUAN

期刊论文

Characteristics of typical dissolved black carbons and their influence on the formation of disinfection

期刊论文

oxide for active and intelligent packaging: comparison of anthocyanins source from purple tomato or black

期刊论文

Property-performance relationship of core-shell structured black TiO photocatalyst for environmental

期刊论文

A review on co-pyrolysis of coal and oil shale to produce coke

Xiangchun Liu, Ping Cui, Qiang Ling, Zhigang Zhao, Ruilun Xie

期刊论文

Community diversity and distribution of ammonia-oxidizing archaea in marsh wetlands in the black soil

Chunhong Chen, Hong Liang, Dawen Gao

期刊论文

中美页岩气成藏条件、分布特征差异研究与启示

李建忠,李登华,董大忠,王社教

期刊论文

Contribution of black carbon to nonlinearity of sorption and desorption of acetochlor on sediment

Jianqiu LIU, Yaobin ZHANG, Hong CHEN, Yazhi ZHAO, Xie QUAN

期刊论文

Effect of carbon black on the dynamic moduli of asphalt mixtures and its master curves

Chuangmin LI, Fanbo NING, Yuanyuan LI

期刊论文